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论文题目: Anomalous phase transition of Bi- doped Zn2GeO4 investigated by electrical conductivity and Raman spectroscopy under high pressure
全部作者: Wu, Lei; Dai, LiDong; Li, HePing; Hu, Haiying; Zhuang, YuKai; Liu, KaiXiang
第一作者: Wu, Lei
联系作者: DAI Lidong
刊物名称: JOURNAL OF APPLIED PHYSICS
发表年度: 2017
卷: 121
期: 12
页码:
摘要:
We present a pressure-induced amorphization for pure and 0.5 mol. % Bi (3+) doped Zn2GeO4 samples, measured by high pressure Raman spectroscopy and high resolution transmission electron microscopy. Pressure-induced conductivity switching phenomena were discovered for both samples at around similar to 7.01 GPa and similar to 11.11 GPa, respectively, which closely correlated with the crystalline-to-amorphous transformation. The detailed conduction mechanism and the defect reaction process at high pressure indicate that the application of pressure could efficiently manipulate the microstructure and electrical performance of rare-earth doped polycrystalline materials, and therefore holds great promise for numerous applications in the future. Published by AIP Publishing.
论文链接: https://aip.scitation.org/doi/10.1063/1.4979311